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A highly efficient β‐arabinofuranosylation utilizing boron‐mediated aglycon delivery (BMAD) is presented by Kazunobu Toshima, Daisuke Takahashi, and co‐workers in their Research Article (e202307015). The glycosylations proceeded smoothly for a variety of diols, triols, and unprotected sugar acceptors under mild conditions with predictable regioselectivity and complete β‐stereoselectivity. Furthermore,...
Regio‐ and stereoselective formation of the 1,2‐cis‐furanosidic linkage has been in great demand for efficient synthesis of biologically active natural glycosides. In this study, we developed a regioselective and β‐stereospecific d‐/l‐arabinofuranosylation promoted by a boronic acid catalyst under mild conditions. The glycosylations proceeded smoothly for a variety of diols, triols, and unprotected...
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