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Lithium–selenium batteries are characterized by high volumetric capacity comparable to Li–S batteries, while ≈1025 times higher electrical conductivity of Se than S is favorable for high‐rate capability. However, they also suffer from the “shuttling effect” of lithium polyselenides (LPSes) and Li dendrite growth. Herein, a multifunctional Janus separator is designed by coating hierarchical nitrogen‐doped...
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