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Kinetics of gold(III) chloride complex ions reduction with dimethylamine borane and precipitation of gold nanoparticles was investigated. The influence of concentrations of reductant, gold(III) chloride complex ions, neutral salt and chloride ions as well as temperature on the process was reported. Experimental results were used to determine parameters in the Arrhenius equation. A set of reactions...
Kinetics of reaction between palladium(II) chloride complex and dimethylamineborane was investigated. Experiments were carried out at various initial concentrations of palladium(II) complex ions and reductant, ionic strengths and temperatures. Rate constants of the reaction were determined. Parameters of Arrhenius equation (Ea=47.4±8.0kJ/mol, A=3.76×108s−1) were calculated from empirical kinetic data...
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