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Lithium (Li) metal, a promising anode for high‐energy‐density rechargeable batteries, typically grows along the low‐surface energy (110) plane in the plating process, resulting in uncontrollable dendrite growth and unstable interface. Herein, an unexpected Li growth behavior by lanthanum (La) doping is reported: the preferred orientation turns to (200) from (110) plane, enabling 2D nuclei rather than...
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