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Polymerization of vinyl acetate is achieved under the photocatalysis of TiO 2 nanoparticles in aqueous suspensions. It is clarified that the photocatalytic polymerization is due to the acetic acid generated from the hydrolysis of vinyl acetate. 13 C NMR analysis further demonstrates by using 2- 13 C-acetic acid that vinyl acetate is initiated by methyl radical that results...
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