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C–S bond formation reactions are widely distributed in the biosynthesis of biologically active molecules, and thus have received much attention over the past decades. Herein, we report intramolecular C–S bond formation by a P450 monooxygenase, TleB, which normally catalyzes a C−N bond formation in teleocidin biosynthesis. Based on the proposed reaction mechanism of TleB, a thiol‐substituted substrate...
Biokatalyse Die Cytochrom P450 Monooxygenase TleB katalysiert die C‐S‐Bindungsbildung, um ein schwefelhaltiges Indolactam und eine ungewöhnliche 6/5/8‐tricyclische Verbindung zu erzeugen, wie T. Ohwada und I. Abe in ihrem Forschungsartikel auf S. 4017 berichten.
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