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A rare heterometallic cluster-based polymer [Cu4(Hbhea)4(μ2-OCH3) K(CH3OH))]n·(H2O)n (1) (H3bhea = 2-[bis-(2-hydroxy-ethyl)-amino]-ethanesulfonic acid), has been synthesized and structurally determined by single crystal X-ray diffraction, elemental analysis. Crystallographic unit of 1 consists of four Cu(II), four Hbhea ligands, one methanol molecule, one methanol anion, one K ion and one crystal...
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