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Ein CF3‐Radikal kann in einem phosphankatalysierten Einelektronentransferprozess aus dem Togni‐Reagens generiert werden. In ihrer Zuschrift auf S. 4113 ff. nutzen B. Tan, X.‐Y. Liu und Mitarbeiter diese Chemie zur Entwicklung der ersten Phosphan‐katalysierten, radikalischen Tandemreaktion zur gleichzeitigen Funktionalisierung eines Alkens und einer β‐C‐H‐Bindung eines Aminderivats. Diese Reaktion...
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