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The–(G°(T)–H°(0))/T Gibbs energy functions have been calculated for Sc2 at Т = 2000 K in the context of recent data on the low-lying electron states for this kind of molecules. In particular, some recent experimental results on the vapor composition over scandium are presented in this study. The data on the measured scandium vapor composition have been processed using the evaluated Gibbs energy function...
A critical analysis of experimental and theoretical data on the structure and vibration frequencies of scandium trihalides molecules is performed. The values of molecular constants are chosen, and the thermodynamic functions are calculated in the temperature range T = 298.15–6000 K. The obtained values are introduced into the database of the IVTANTERMO software package. The sublimation enthalpies...
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