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Local structure of Cr 2+ ions in CdS and CdTe is similar with a D 2d symmetry, but a contrary electronic fine structures for CdS:Cr 2+ (b 20 < 0) and CdTe:Cr 2+ (b 20 > 0) have been found in EPR experiments. We demonstrate that this is due to the contribution from the spin-orbit coupling associated with the ligand...
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