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It is shown that the effective synthesis of methanol may be performed in the presence of ultrafine catalyst systems formed by drop thermolysis in situ in a slurry reactor. Using the X-ray powder diffraction and FTIR spectroscopy data on the evolution of Cu–Zn–Al-containing catalyst dispersion during activation and catalysis, possible reasons for ultrafine catalyst deactivation are considered.
The review summarizes data published in the scientific and patent literature on the synthesis of methanol in slurry reactors using finely divided heterogeneous catalysts suspended in liquids. Variants of methyl alcohol production in inert liquid media and with the use of an active liquid phase have been considered. The advantages of the slurry technology over the conventional gas-phase process of...
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