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The energy characteristics of the dehydration and dehydrogenation of ethanol have been evaluated by quantum-chemical analysis. It has been found that the dehydration of ethanol is an energetically favorable reaction. By analysis of the multiroute decomposition of hydrogen peroxide, the energy characteristics of individual reactions of the formation of hydroxyl and peroxide radicals and hydrogen and...
A synergistic effect has been revealed upon hydrogen peroxide initiation of the catalytic ethanol-to-divinyl conversion process, proposed by S.V. Lebedev, on the (K2O)ZnO/γ-Al2O3 catalyst. The efficiency of the initiator has been examined, depending on the form of aluminum oxide, hydrogen peroxide concentration in the system, and the linear velocity of the feed stream. The behavior of the process...
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