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Cyclohexanone is an important intermediate in the manufacture of polyamides in chemical industry, but direct selective hydrogenation of phenol to cyclohexanone under mild conditions is a challenge. Hydrogenation of phenol to cyclohexanone has been investigated in the presence of the composite catalytic system of Pd/C-heteropoly acid. 100% conversion of phenol and 93.6% selectivity of cyclohexanone...
The novel water-soluble and sterically hindered phthalocyanine complexes, i.e. iron(III) tetra-(4-carboxyphenoxy)phthalocyanine (3) and iron(III) tetra-(8-quinolineoxy-5-sulfonicacid)phthalocyanine (4) were synthesized for fast detection of phenolic pollutants. These two FePc complexes exhibited the high catalytic activity in the chromogenic reactions of phenolic pollutants. Five phenolic substrates,...
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