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Conjugated polymers usually form crystallized and amorphous regions in the solid state simultaneously, making it difficult to accurately determine their precise microstructures. The lack of multiscale microstructures of conjugated polymers limits the fundamental understanding of the structure–property relationships in polymer‐based optoelectronic devices. Here, crystals of two typical conjugated polymers...
In article number 2006794, Jian Pei and co‐workers report the microwire crystal and crystal structures of two widely used conjugated polymers. High electron mobility and a lower hopping energy barrier are achieved in field‐effect transistors fabricated using the polymer crystals. The crystal structures are successfully determined through the combination of powder X‐ray diffraction and molecular modeling...
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