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A silver-catalyzed [3+2+1] annulation of amidines with benzyl isocyanide toward 2,4-diaryl-1,3,5-triazines was developed. A variety of symmetrical and unsymmetrical products were obtained in moderate to good yields. This work also features an oxidant-free approach to 2,4-disubstituted triazines.
Methyleneaziridines reacted with diynes to generate fused anilines. This reaction involved a C2–C3 bond cleavage of methyleneaziridine. This work provides a new reaction pattern of methyleneaziridine.
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