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Relations between the main parameters characterizing the structure of ellipsoidal micelles of ionic surfactants in aqueous solutions and the geometric sizes of micelles are derived and analyzed within the framework of the model of the two-axial ellipsoid of revolution. Conditions of the existence of “continuous” and hollow ellipsoidal micelles are discussed using the generalized Gibbs-Curie principle...
The process of asymmetrization of spherical micelles in an aqueous sodium decyl sulfate solution is studied by scanning calorimetry. This process represents the intermicellar phase transition with an equilibrium temperature of 300 K occurring at a sodium decyl sulfate concentration of 0.12 mol/kg. The partial molar heat capacities of sodium decyl sulfate in a solution are determined and the thermodynamic...
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