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Constructing multiple functional geometric frustration magnets is a hot topic in solid state chemistry and material science. Herein, a two‐dimensional (2D) parallel interpenetrating “star” net complex [HDMPDA][Fe6(μ3‐O)2(μ‐O2CH)15] (1) was obtained successfully with HDMPDA (DMPDA=N, N’‐dimethyl‐1,3‐propanediamine) as charge balancer. The dipole reorientation of the rotator [HDMPDA]+ in the complex...
In this work, by using two kinds of viologen ligands three POM‐based Compounds were obtained under hydrothermal conditions, namely [AgI(bmypd)0.5(β‐Mo8O26)0.5] (1) (bmypd ⋅ 2Cl=1,1′‐[Biphenyl‐4,4′‐bis(methylene)]bis(4,4′‐bipyridyinium)dichloride), [AgI2(bypy)4(HSiW12O40)2] ⋅ 14H2O (2) and [AgI(bypy)(γ‐Mo8O26)0.5] (3) (bypy⋅Cl=1‐Benzyl‐4,4′‐bipyridyinium chloride). The structures were characterized...
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