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CO2 methanation over supported nickel catalysts attracts an increasing attention. However, the mechanism with it is still in debate. It is confirmed here that the structure of Ni/TiO2 catalyst has a significant effect on CO2 methanation. The catalyst with Ni (111) as the principal exposing facet shows higher activity with higher methane selectivity. The maximum activity for CO2 methanation is obtained...
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