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Although pyrazine‐linked hybrid ultramicroporous materials (HUMs, pore size <7 Å) are benchmark physisorbents for trace carbon dioxide (CO2) capture under dry conditions, their affinity for water (H2O) mitigates their carbon capture performance in humid conditions. Herein, we report on the co‐adsorption of H2O and CO2 by TIFSIX‐3‐Ni—a high CO2 affinity HUM—and find that slow H2O sorption kinetics...
Although pyrazine‐linked hybrid ultramicroporous materials (HUMs, pore size <7 Å) are benchmark physisorbents for trace carbon dioxide (CO2) capture under dry conditions, their affinity for water (H2O) mitigates their carbon capture performance in humid conditions. Herein, we report on the co‐adsorption of H2O and CO2 by TIFSIX‐3‐Ni—a high CO2 affinity HUM—and find that slow H2O sorption kinetics...
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