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This review describes a series of studies on the Na+ superionic conducting glass-ceramics with Na5YSi4O12 (N5)-type structure synthesized using the composition formula of Na3+3x−yR1−xPySi3−yO9 for a variety of rare earth elements, R, under the appropriate composition parameters. In the crystallization of N5-type glass-ceramics, its relatives (Na3YSi3O9 (N3)- and Na9YSi6O18 (N9)-type glass-ceramics)...
Glass-ceramics of the boron-, aluminium- or gallium-containing Na 5 RSi 4 O 12 -type (R=rare earth; Y) Na + -superionic conductors were prepared by crystallization of glasses with the composition Na 3+3x+y Y 1−x X y Si 3−y O 9 (X=B; NaYBSi, X=Al; NaYAlSi, X=Ga; NaYGaSi) (x=0.2, y=0.1). The crystallization kinetics of the glasses...
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