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The catalytic activity of 2wt% Ir/TiO 2 in alcohol oxidation with molecular oxygen was enhanced by high-temperature reduction (673–873K) of the catalyst in a hydrogen stream. Wide variety of alcohols were converted efficiently into corresponding carbonyl compounds with 2wt% Ir/TiO 2 reduced at 723K. Kinetic analysis revealed that the alcohol adsorption was enhanced by high-temperature...
A TiO 2 supported Ir catalyst prepared by the conventional impregnation method exhibited efficient catalytic activity toward the oxidation of organic compounds with molecular oxygen. Aromatic alcohols and alkylarenes selectivity afforded the corresponding carbonyl compounds in high yield under mild conditions. The reaction was quenched by removing the catalyst with filtration suggesting that...
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