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Phase relations in CaAl4Si2O11 were examined at 12–23GPa and 1000–1800°C by multianvil experiments. A three-phase mixture of grossular, kyanite and corundum is stable below about 13GPa at 1000–1800°C. At higher pressure and at temperature below about 1200°C, a mixture of grossular, stishovite and corundum is stable, indicating the decomposition of kyanite. Above about 1200°C, CaAl4Si2O11 CAS phase...
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