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Mono-Schiff base Mn(III) complexes of general formula MnL2Cl, with pendant aza-crown or morpholino substituents, have been synthesized and investigated as catalysts for the epoxidation of styrene at ambient temperature and pressure. The highest conversion yield of styrene and selectivity for epoxide were 40 and 96%, respectively. These complexes have been also studied as catalysts for the aerobic...
Schiff base Co(II) complexes, CoL 21 –CoL 26 with aza-crown or morpholino pendants were synthesized. The oxygenation constants (KO2) of these complexes in MeOCH2CH2OMe solution were measured over the range of −5 to 25 °C, and the thermodynamic parameters (∆H0, ∆S0) for oxygenation were calculated based on these KO2 values. The effects of different substituents on the Schiff base ligand with respect...
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