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Ether solvents with superior reductive stability promise excellent interphasial stability with high‐capacity anodes while the limited oxidative resistance hinders their high‐voltage operation. Extending the intrinsic electrochemical stability of ether‐based electrolytes to construct stable‐cycling high‐energy‐density lithium‐ion batteries is challenging but rewarding. Herein, the anion‐solvent interactions...
Ether solvents with superior reductive stability promise excellent interphasial stability with high‐capacity anodes while the limited oxidative resistance hinders their high‐voltage operation. Extending the intrinsic electrochemical stability of ether‐based electrolytes to construct stable‐cycling high‐energy‐density lithium‐ion batteries is challenging but rewarding. Herein, the anion‐solvent interactions...