The Infona portal uses cookies, i.e. strings of text saved by a browser on the user's device. The portal can access those files and use them to remember the user's data, such as their chosen settings (screen view, interface language, etc.), or their login data. By using the Infona portal the user accepts automatic saving and using this information for portal operation purposes. More information on the subject can be found in the Privacy Policy and Terms of Service. By closing this window the user confirms that they have read the information on cookie usage, and they accept the privacy policy and the way cookies are used by the portal. You can change the cookie settings in your browser.
The trigonal bipyramidal structure of trichloromethyl-tetrachlorophosphorane CCl3PCl4 and bis(trichloromethyl)trichlorophosphorane (CCl3)2PCl3 molecules with apical CCl3 groups is responsible for steric hindrances to reorientations of these groups around the C–P bond. The intramolecular barriers to CCl3 reorientations calculated for the two phosphoranes (Hartree–Fock method using the 6-31G(d) basis...
Set the date range to filter the displayed results. You can set a starting date, ending date or both. You can enter the dates manually or choose them from the calendar.