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The atomic and electronic structures of LnAl 2 (Ln=Y, La and Lu) on Al sites were characterized by 27 Al solid state NMR spectroscopy. 27 Al isotropic metallic shifts have been determined in these cubic laves phases under both static and magic angle spinning (MAS) conditions. Based on band structure calculations, we found a strong correlation of 27 Al isotropic metallic...
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