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Inorganic macrocycles, based on non‐carbon backbones, present exciting synthetic challenges in the systematic assembly of inorganic molecules, as well as new avenues in host–guest and supramolecular chemistry. Here we demonstrate a new high‐yielding modular approach to a broad range of trimeric and hexameric S‐ and Se‐bridged inorganic macrocycles based on cyclophosphazane frameworks, using the building...
Organische Chemie trifft Makrocyclenchemie:Die Bildung von großen anorganischen Makrocyclen mit über Schwefel‐ oder Selenatome verknüpften Phosphazan‐Einheiten gelingt mit einer Eintopfmethode, die D. S. Wright et al. in der Zuschrift auf S. 9215 ff. beschreiben. Vielfältige organische Substituenten können eingeführt werden, sodass die gezielte Abstimmung der sterischen und elektronischen Eigenschaften...
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