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The effect of pretreatment procedure on catalytic performance during Fischer–Tropsch synthesis (FTS) of unpromoted cobalt on alumina (15 %Co/Al2O3) catalyst was studied in a fixed-bed reactor. Pure carbon monoxide or a mixture of hydrogen and carbon monoxide were used as reducing agents prior to FTS. Pretreatments with pure CO result in low activity and high selectivity to methane and gaseous hydrocarbons...
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