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Eine Anthologie fluorhaltiger Corannulenblüten bildet das Herzstück einer chemischen Landschaft, die von der Elektronenstrukturtheorie umrissen wurde und nun experimentell ausgefüllt wird. Darüber schwebt die chemische Transformation, die zu der neuesten Blüte, dem sym‐Pentafluorcorannulen, führt, dessen Kristallpackung das empirische Fundament bildet, aus dem die Blüten sprießen. Für Details siehe...
Ten sym‐penta and deca‐X substituted corannulenes (1–10; X=H, F, CH3, or CF3) define a library of fluorous compounds comprising high symmetry non‐planar aromatic compunds. They provide a group of structurally similar, yet physically distinct structures manifesting special chemical behavior related to their degree of fluorination. Owing to their bowl forms, corannulene derivatives are distinct from...
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