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A photolatent base ((1,5-diazabicyclo [4.3.0]non-5-ene) DBN) is used for the first time as photocatalyst for the curing of a formulation, which undergoes crosslinking by Michael addition reaction between acetoacetate and acrylate groups together with the reduction of graphene oxide.The reduction degree of graphene oxide during in situ irradiation is monitored by XPS analysis. The effect of the graphene...
Poor dispersion of graphene in non-polar polymer matrices creates composites with limited applications. A method to improve the dispersion of graphene in polyethylene (PE) via blending PE with oxidized PE (OPE) is examined. Graphene was produced by simultaneous thermal exfoliation and reduction of graphite oxide. Nanocomposites of graphene with PE as well as graphene with PE/OPE-blends were prepared...
Biorenewable polyamide-11 (PA11) is blended with partially biorenewable polyamide-6,10 (PA610) to produce thermoplastics of varying renewable carbon content. DSC thermograms show melting point depression for the PA610 crystals with increasing PA11 composition thus indicating that the two polyamides are fully miscible in the melt; the blends exhibit crystallization induced phase separation. Wide angle...
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