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To boost the electrochemical performance of MnCO3 (MC) microspheres, binary SbxMn1−xCO3 (x = 1/3, 1/2 and 2/3) microspheres, labeled SMC-12, SMC-11 and SMC-21, respectively, were prepared using a solvothermal method. A 3D conductive network of carbon nanotubes (CNT) was also successfully built from the inside to the surface of the SMC-12 microspheres to promote electronic and ionic transportation...
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