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The solvent-free catalytic oxidation of toluene using molecular oxygen over metalloporphyrin/N-hydroxyphthalimide (NHPI)/cetyl trimethyl ammonium bromide (CTAB) has been developed. The results showed that the type of metalloporphyrin used, catalyst loading, reaction temperature, and the flow rate of oxygen all influenced the conversion of toluene and the selectivities of the products. Furthermore,...
In this paper, a series of nanoparticle bonded metalloporphyrins with different saturation magnetization were synthesized by a modified silanation method. Under geomagnetic field (5 × 10−5 T), with the increase of the saturation magnetizations, the growth rate of yields of cyclohexanol in the cyclohexane oxidation with iodosylbenzene catalyzed by these nanoparticle bonded metalloporphyrins followed...
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