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Enthalpies of dilution of formamide in aqueous n-propanol, 1,2-propanediol and glycerol solutions have been determined by isothermal calorimetry at 298.15K. The values of dilution enthalpy were used to determine homogeneous enthalpic interaction coefficients which characterize the interactions of formamide in alcohol solutions. The variations of the enthalpic pairwise interaction coefficients with...
A commercial flow-mixing isothermal calorimeter was tested by measuring heat of mixing curves for exothermic, endothermic, S-shaped and double minimum molar excess enthalpy mixtures at high pressure. The results show this calorimeter is able to produce good quality data. Molar excess enthalpies for ethyl acetate mixed with a series of simple alkanols were measured at T=298.15K and p=10MPa.
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