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Copper(II) complexes [Cu(acactn)H 2 O] 2 (1) and [Cu 2 (acactn) 2 KClO 4 ] 2 (2), where H 2 acactn is a tetradentate Schiff base bis(acetylacetone)trimethylenediimine, have been prepared and characterized by IR, CV and X-ray single crystal structure analyses. The ligand H 2 acactn is strongly metallophilic to stabilize Cu(II) ion with...
The square-planar complex [Cu(MIMH)(CH3CO2)](ClO4) (1) (MIMH = [(4-methylimidazol-5-yl)methylene]histamine) was prepared and structurally characterized. Complex 1 crystallizes in the monoclinic space group P21/n with a = 10.5331(10), b = 12.6177(10), c = 12.9773(10) Å, β = 107.710(10)°, V = 1643.0(2) Å3, and Z = 4. Single-crystal X-ray analysis reveals that the copper(II) atom in 1 has a distorted...
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