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High-valent oxo metalloporphyrins have been known as reactive intermediates in the catalytic cycles of many heme enzymes and in the oxidation reactions mediated by synthetic metalloporphyrins. In this review, we survey studies of high-valent oxo metalloporphyrins in the past decade. In Sect. 2, electronic structures and magnetic properties of compound I and compound II species in various heme enzymes...
High valent oxo iron porphyrins have been prepared and characterized as models for compounds-I and compounds-II in heme enzymes. In this review, we survey studies of high valent oxo iron porphyrin complexes. Spectroscopic properties and reactivities of oxo iron(IV) porphyrin π-cation radical complexes are summarized. Electron-withdrawing effects of meso-substituents and pyrrole β-substituents on the...
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