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The reduction thermodynamics (ΔHrc∘′ and ΔSrc∘′) and the kinetics of electron transfer for spinach plastocyanin adsorbed on a polycrystalline gold electrode coated with a mixed SAM made of 11-mercapto-1-undecanol and 11-mercapto-1-undecanoic acid were determined through cyclic voltammetry. The adsorbed protein experiences a marked enthalpic stabilization of the oxidized state, likely due to the electrostatic...
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