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Cubane has been known about for more than half a century, but methods for direct functionalization of commercial cubane derivatives remain somewhat limited. The possibility of using electrochemical methods to transform cubane carboxylic acids presented an intriguing possibility, leading to the development of anodic decarboxylative ether formation in flow. The image, created by Noémie Collin, shows...
The highly strained cubane system is of great interest as a scaffold and rigid linker in both pharmaceutical and materials chemistry. The first electrochemical functionalisation of cubane by oxidative decarboxylative ether formation (Hofer–Moest reaction) was demonstrated. The mild conditions are compatible with the presence of other oxidisable functional groups, and the use of flow electrochemical...
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