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This study is concerned with the ternary compounds RELixSn2 (RE=La–Nd, Sm, and Gd; 0≤x<1), which have been previously thought to be the stoichiometric RELiSn2 phases. These materials crystallize with the base-centered orthorhombic space group Cmcm (No. 63), and can be formally assigned with the CeNiSi2 structure type (Pearson symbol oC16). Our systematic single-crystal X-ray diffraction studies...
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