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The preparation of soluble organometallic hydroxides is a key step in the preparation of organometallic oxides containing the heterobimetallic M–O–M′ unit. Compounds of composition LMOH where M is a Main Group metal (Ca, Sr, Al, Ga, Ge, Sn) and transition metal (Zr, Hf) are summarized. The reactions of Cp3Ln (Ln = Yb, Dy, Er, Sm) with several hydroxides to yield compounds with the skeletons M(μ‐O)...
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