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Through the labile coordination sites of a robust phosphonate‐stabilized titanium–oxo cluster, 14 O‐donor ligands have been successfully introduced without changing the cluster core. The increasing electron‐withdrawing effect of the organic species allows the gradual reduction of the bandgaps of the {Ti6} complexes. Transition‐metal ions are then incorporated by the use of bifunctional O/N‐donor ligands,...
Clusterchemie In ihrer Zuschrift auf S. 5246 ff. zeigen L. Zhang, J. Zhang et al., dass die labilen Koordinationsstellen eines {Ti6}‐Clusters genutzt werden können, um dessen Oberfläche zu funktionalisieren.
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