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Transition-metal-catalyzed CH functionalization has emerged as attractive tools for organic synthesis. These catalytic reactions typically need strong chemical oxidants, which possess significant disadvantages, including high cost, poor atom economy, and the formation of undesired byproducts. To overcome these issues, transition-metal-catalyzed CH functionalization via electrochemical oxidation has...
Diastereoselective addition of a number of Grignard reagents to chiral p-toluene sulfinimines 2b-2d under the mediation of copper salts afforded various protected α-branched amines.
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