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The 1-methylbenzotriazole ligand (1-Mebta) has been successfully incorporated into four new 1-D coordination polymers of general formula [M II (dca) 2 (1-Mebta) 2 ] (M=Mn (1), Fe (2) and Cu (3)) and [Cu II (tcm) 2 (1-Mebta) 2 ] (4) containing the dicyanamide (N(CN)2-,dca-) or tricyanamide (C(CN)3-,tcm-) μ 1,5 -bridging ligands. Magnetic susceptibility...
Coordination polymers containing dicyanamide (N(CN) 2- , dca) or tricyanomethanide (C(CN) 3- , tcm) bridging ligands are described from the perspective of their structure and magnetism. The binary compounds α-M(dca) 2 form an isostructural series (M=Cr, Mn, Fe, Co, Ni, Cu) having a single rutile-like network that involves μ 1,3,5 -dca bridging...
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