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Wasser‐DMSO‐Wechselwirkungen wurden mittels IR‐Spektroskopie analysiert. In ihrer Zuschrift auf S. 11533 zeigen C. R. Baiz et al., dass die Wasserstoffbrückenpopulation in binären Mischungen direkt quantifiziert werden kann und die molekularen Ensembles mit makroskopischen Lösungseigenschaften korreliert werden können. Die im Titelbild zu sehenden Fische repräsentieren die in Gruppen aus dem Wasser...
Dimethyl sulfoxide (DMSO) disrupts the hydrogen‐bond networks in water. The widespread use of DMSO as a cosolvent, along with its unusual attributes, have inspired numerous studies. Herein, infrared absorption spectroscopy of the S=O stretching mode combined with molecular dynamics and quantum chemistry models were used to directly quantify DMSO/water hydrogen‐bond populations in binary mixtures....
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