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The kinetic method for analysing consecutive reactions under isothermal conditions has been developed further. An approach to assessing the correspondence of the calculated values of the rate constants to the exact steps is suggested. As an example of application of this method, the consecutive quaternizations between N,N,N ,N -tetramethyl-1,3-propylenediamine and bromobutane, which is a model...
The relationship between the rate of enthalpy change of a chemical reaction and the formation rates of its constituents is derived, and then transformation equations for the thermokinetics of single-substrate enzyme-catalyzed reactions are deduced, and the validity and prerequisite of application of the chemical amplification of enthalpy changes to thermokinetic investigations are proved.A reduced-extent...
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