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In the framework of the parametric method 3 quantum chemical approximation reasonable values are obtained for the thermo-dynamic characteristics of the cluster formation for the fatty alcohol series CnH2n+1OH (n = 8–16) with various structures at the air/water interface. The calculated values of the enthalpy, the entropy and the Gibbs energy for the formation of a definite cluster structure can be...
Recent progress in studies of the main characteristics of supramolecular assemblies formed by interfacial molecular recognition between an amphiphilic monolayer and a non-surface-active species, which is dissolved in the aqueous subphase, by complementary hydrogen bonding and/or electrostatic interaction at the air–water interface is reviewed.Systems consisting of an amphiphilic melamine-type monolayer...
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