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Nonmetal‐to‐metallo‐aromatic‐ring coordination is reported by Jun Li, Zhikun Wu et al. in their Research Article (e202313491). The unexpected coordination, which is different from the common organo‐aromatic‐ring‐to‐metal coordination, serves single‐atom‐layered Pd nanoclusters with exceptional stability. Furthermore, the dominant horizontal electron transition induces strong optical absorption and...
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