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The coadsorption of aminomethylidyne (CNH 2 ) and hydrogen on Pt(111) has been studied with reflection absorption infrared spectroscopy (PAIRS). Previous work has shown that when a clean Pt(111) surface is exposed to HCN at temperatures of 240-350 K, the HCN reacts to produce the CNH 2 species along with adsorbed CN. The IR spectra at intermediate CNH 2 coverages show that...
Normal-mode calculations were used to analyze the reflection absorption infrared spectra of six hydrogenated cyanogen (C 2 N 2 ) isotopomers formed by the reactions of 12 C 214 N 2 , 12 C 215 N 2 and 13 C 214 N 2 with H 2 and D 2 on Pt(111) at 300 K....
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