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In this paper we report a brief review of the palladium–catalyzed olefination and amination of aryl chlorides. Special emphasis is given on the efficiency of known catalysts. Best turnover numbers (TON up to 40,000) known to date for Heck reactions are displayed by palladacycle catalysts, e.g., 1 in the presence of salts as co–catalysts. Model studies show that the catalyst productivity is strongly...
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