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Effect of nanoclay on the kinetics of atom transfer radical bulk homo- and copolymerization of styrene (St) and methyl methacrylate (MMA) initiated with CCl 3 -terminated poly (vinyl acetate) macroinitiator at 90°C was investigated. CuCl/PMDETA was used as a catalyst system. Results showed that nanoclay significantly enhances the homopolymerization rate of MMA. It was attributed to the activated...
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