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X-ray photoelectron spectroscopy was used to measure the valence-band offset (ΔEV) of MgO/InP heterostructure. Two sets of core level pairs in the MgO/InP system were used to demonstrate the accuracy of the calculation, the ΔEV value was the same (5.33 ± 0.15 eV) when using the In 3d3/2, Mg 2p pair and In 3d5/2, Mg 2p pair, indicating our calculations are accuracy and reasonable. Taking the band gaps...
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